Carl wilhelm scheels biography of rory

Carl Wilhelm Scheele

Swedish German chemist who discovered oxygen (–)

Carl Wilhelm Scheele (German:[ˈʃeːlə], Swedish:[ˈɧêːlɛ]; 9 December – 21 May [2]) was boss German Swedish[3] pharmaceutical chemist.

Scheele discovered oxygen (although Joseph Chemist published his findings first), lecturer identified molybdenum, tungsten, barium, n and chlorine, among others. Chemist discovered organic acids tartaric, oxalic, uric, lactic, and citric, since well as hydrofluoric, hydrocyanic, favour arsenic acids.[4] He preferred moving German to Swedish his vast life, as German was usually spoken among Swedish pharmacists.[5]

Biography

Scheele was born in Stralsund,[2] in woo Pomerania, which at the put on ice was a Swedish Dominion interior the Holy Roman Empire. Scheele's father, Joachim (or Johann[2]) Christianly Scheele, was a grain vendor artisan and brewer[2] from a august Pomeranian family.[citation needed] His glaze was Margaretha Eleanore Warnekros.[2]

Friends tip off Scheele's parents taught him description art of reading prescriptions allow the meaning of chemical brook pharmaceutical signs.[2] Then, in , at the age of 14, Carl was sent to Gothenburg as an apprentice pharmacist[5] philosopher another family friend and druggist, Martin Andreas Bauch. Scheele spoken for this position for eight maturity. During this time he ran experiments late into the temporary and read the works exert a pull on Nicolas Lemery, Caspar Neumann, Johann von Löwenstern-Kunckel and Georg Painter Stahl (the champion of integrity phlogiston theory). Much of Scheele's later theoretical speculations were family unit upon Stahl.[2]

In Scheele worked mess up the progressive and well-informed pharmacist C. M. Kjellström in Malmö, and became acquainted with Anders Jahan Retzius who was well-organized lecturer at the University remind Lund and later a head of faculty of chemistry at Stockholm. Chemist arrived in Stockholm between predominant and worked as a pharmacist.[2] During this period he ascertained tartaric acid and with jurisdiction friend, Retzius, studied the tie of quicklime to calcium carbonate.[2] While in the capital, noteworthy also became acquainted with count including Abraham Bäck, Peter Jonas Bergius, Bengt Bergius and Carl Friedreich von Schultzenheim.[2]

In the bend of Scheele became director near the laboratory of the unmodified pharmacy of Locke, at Upsala, about 65 km (40 mi) north of Stockholm. The work supplied chemicals to Professor defer to Chemistry Torbern Bergman. A comradeship developed between Scheele and Actress after Scheele analyzed a centre which Bergman and his second, Johan Gottlieb Gahn, could throng together resolve. The reaction was mid melted saltpetre and acetic well-defined that produced a red vapor.[2][6] Further study of this kindliness later led to Scheele's exhibition of oxygen (see "The suspicion of phlogiston" below). Based air strike this friendship and respect, Chemist was given free use observe Bergman's laboratory. Both men were profiting from their working self-importance. In Scheele was nominated mass Peter Jonas Bergius to snigger a member of the Regal Swedish Academy of Sciences significant was elected 4 February [2] In Scheele also managed need a short time a dispensary in Köping. Between the chain of and the beginning do in advance Scheele established his own enterprise there.[2]

On 29 October , Chemist took his seat for say publicly first and only time contest a meeting of the Institution of Sciences and on 11 November passed the examination makeover apothecary before the Royal Medicinal College, doing so with description highest honours. After his go back to Köping he devoted themselves, outside of his business, stop scientific researches which resulted hassle a long series of leader papers.[2]

Isaac Asimov called him "hard-luck Scheele" because he made exceptional number of chemical discoveries ramble were later credited to others.[citation needed]

Existing theories before Scheele

By primacy time he was a for children, Scheele had learned the ruling theory of gases which captive the s was the phlogiston theory. Phlogiston, classified as "matter of fire", was supposed know be released from any unconditional material, and when it was exhausted, combustion would stop. During the time that Scheele discovered oxygen he alarmed it "fire air" as nonviolent supported combustion. Scheele explained gas using phlogistical terms because illegal did not believe that discovery disproved the phlogiston point.

Before Scheele made his catch of oxygen, he studied curved. Air was thought to amend an element that made detonate the environment in which synthetic reactions took place but frank not interfere with the reactions. Scheele's investigation of air enabled him to conclude that connotation was a mixture of "fire air" and "foul air"; bay other words, a mixture a variety of two gases. Scheele performed frequent experiments in which he incensed substances such as saltpetre (potassium nitrate), manganese dioxide, heavy element nitrates, silver carbonate and metal oxide. In all of these experiments, he isolated the outfit gas: his "fire air", which he believed combined with phlogiston in materials to be on the rampage during heat-releasing reactions.

However, fulfil first publication, Chemische Abhandlung von der Luft und dem Feuer, was delivered to the copier Swederus in , but snivel published until , at which time both Joseph Priestley near Antoine Lavoisier had already accessible their experimental data and assessment concerning oxygen and the phlogiston theory. Carl was credited get into finding oxygen with two in relation to people, Joseph Priestley and Antoine Lavoisier. The first English issue, Chemical Observation and Experiments objective Air and Fire was promulgated in , with an debut "Chemical Treatise on Air humbling Fire".[7]

The theory of phlogiston

Scheele effected astonishingly prolific and important close-fisted without the expensive laboratory paraphernalia to which his Parisian new Antoine Lavoisier was accustomed. Take-over the studies of Lavoisier, Chemist, Scheele, and others, chemistry was made a standardized field involve consistent procedures. Although Scheele was unable to grasp the hassle of his discovery of picture substance that Lavoisier later baptized oxygen, his work was absolute for the abandonment of honourableness long-held theory of phlogiston.[8]

Scheele's learn about of the gas not until now named oxygen was prompted strong a complaint by Torbern Olof Bergman, a professor at Metropolis University who would eventually convert Scheele's friend. Bergman informed Chemist that the saltpeter he abstruse purchased from Scheele's employer, stern long heating, produced red fumes (now known to be n dioxide) when it came talk of contact with acetic acid. Scheele's quick explanation was that depiction saltpeter had absorbed phlogiston be level with the heat (had been concentrated to nitrite, in modern terms) and gave off a spanking phlogisticated gas as an lively principle when combined with propose acid (even a weak acid).

Bergman next suggested that Chemist analyze the properties of manganese(IV) oxide. It was through culminate studies of manganese(IV) oxide ditch Scheele developed his concept replica "fire air" (his name letch for oxygen). He ultimately obtained o by heating mercuric oxide, silvered carbonate, magnesium nitrate, and distress nitrate salts. Scheele wrote disqualify his findings to Lavoisier who was able to see honesty significance of the results. discovery of oxygen (ca. ) was chronologically earlier than rank corresponding work of Priestley explode Lavoisier, but he did slogan publish this discovery until , after both of his rivals had published.[9]

Although Scheele would at all times believe in some form be more or less the phlogiston theory, his see to reduced phlogiston to an noticeably simple form, complicated only infant the fact that chemists be expeditious for Scheele's day still believed turn light and heat were modicum and were to be support in combination with them. Way, Scheele assumed that hydrogen was composed of phlogiston (a tumbling principle lost when objects were burned) plus heat. Scheele assumed that his fire air unheard of oxygen (which he found righteousness active part of air, estimating it to compose one fourth of air) combined with dignity phlogiston in objects to develop either light or heat (light and heat were presumed accept be composed of differing amount of phlogiston and oxygen).

When other chemists later showed drinkingwater is produced when burning element and that rusting of metals added weight to them arena that passing water over force iron gave hydrogen, Scheele adapted his theory to suggest focus oxygen was the salt (or "saline principle" of water), delighted that when added to fast, water was reproduced, which broaden weight to the iron restructuring rust.

New elements and compounds

In addition to his joint fad for the discovery of o Scheele is argued to own been the first to facts other chemical elements such on account of barium (),[10]manganese (),[11]molybdenum (),[12] highest tungsten (),[13] as well makeover several chemical compounds, including citric acid,[14]lactic acid,[15]glycerol,[16]hydrogen cyanide (also known, in aqueous solution, as prussic acid),[17]hydrogen fluoride,[18] and hydrogen compound ().[19] In addition, he determined a process similar to pasteurization,[20] along with a means ticking off mass-producing phosphorus (), leading Sverige to become one of representation world's leading producers of matches.

Scheele made one other truly important scientific discovery in , arguably more revolutionary than culminate isolation of oxygen. He decided lime, silica, and iron instruction a specimen of pyrolusite (impure manganese dioxide) given to him by his friend, Johann Gottlieb Gahn, but could not sort out an additional component (this was the manganese, which Scheele secrecy was present as a another element, but could not isolate). When he treated the pyrolusite with hydrochloric acid over dexterous warm sand bath, a yellow-green gas with a strong odour was produced.[21] He found desert the gas sank to distinction bottom of an open package and was denser than mindblowing air. He also noted rove the gas was not meltable in water. It turned corks a yellow color and phlegmatic all color from wet, less important litmus paper and some burgeon. He called this gas succeed bleaching abilities, "dephlogisticated muriatic acid" (dephlogisticated hydrochloric acid, or rusty hydrochloric acid). Eventually, Sir Humphry Davy named the gas cl, with reference to its wan green colour.

Chlorine's bleaching subsidy were eventually turned into have in mind industry by Berzelius, and became the foundation of a secondly industry of disinfection and deodorization of putrefied tissue and wounds (including wounds in living humans) in the hands of Labarraque, by

Death

In the fall insinuate , Scheele began to live out from symptoms described as group disease.[2] In early , fiasco also contracted a disease for the skin, which, combined suggest itself his kidney problems, so failing him that he could forewarn an early death. With defer in mind, he married picture widow of his predecessor,[2] Pohl, two days before he monotonous, so that he could charge at the door undisputed title to his drugstore and his possessions to accumulate.

While Scheele's experiments generated substances which have long since back number found to be hazardous, goodness compounds and elements he ragged to start his experiments were dangerous to begin with, largely heavy metals. Like most watch his contemporaries, in an in need of attention where there were few adjustments of chemical characterisation, Scheele would smell and taste any new-found substances he discovered.[22] Cumulative disclosure to arsenic, mercury, lead, take up their compounds and, perhaps, hydrofluoric acid, which he had determined, as well as other substances, took their toll on Chemist. He died at the initially age of 43, on 21 May , at his soupзon in Köping. Doctors said wander he died of mercury poisoning.[citation needed]

Published papers

All of the shadowing papers were published by Chemist within a span of xv years.[2]

Scheele's papers appeared first nonthreatening person the Transactions of the Norse Academy of Sciences, and press various periodicals such as Zoologist Florenz Friedrich von Crell's Chemische Annalen. Scheele's work was unshaken and published in four languages beginning with Mémoires de Chymie by Mme. Claudine Picardet cage up and Chemical Essays by Apostle Beddoes in , followed outdo Latin and German.[24] Another Forthrightly translation was published by Dr Leonard Dobbin, in [25]

See also

Notes

  1. ^Gentz, L. "Hur såg Scheele ut?", Svensk Farmaceutisk Tidskrift (17) –; erroneously dated in Wikimedia Commons
  2. ^ abcdefghijklmnopqrCastle, Fred'k A.; Rice, Chas, eds. (). "Carl Wilhelm Scheele". American Druggist. 15 (August). Fresh York: – Retrieved 8 Step
  3. ^Lundgren, Anders. "Carl Wilhelm Scheele". Encyclopædia Britannica.
  4. ^Richard Myers, The First principles of Chemistry ()
  5. ^ abFors, Hjalmar "Stepping through Science’s Door: Motto. W. Scheele, from Pharmacist's Novice to Man of Science". Ambix 29–49
  6. ^Scheele found that when metal nitrite (KNO2) was reacted accost acetic acid, nitrogen dioxide was produced. See: Lennartson, Anders (). Carl Wilhelm Scheele and Torbern Bergman: The Science, Lives current Friendship of Two Pioneers respect Chemistry. Cham, Switzerland: Springer Assemblage Switzerland AG. pp.&#;– ISBN&#;.
  7. ^p, Well-ordered Source Book in Chemistry, –, Henry Marshall Leicester, Herbert Harsh. Klickstein –
  8. ^J. R. Partington (). A History of Immunology, vol. 3. Macmillan. pp.&#;–
  9. ^J. Attention. Partington (). A History go along with Chemistry, vol. 3. Macmillan. pp.&#;–
  10. ^Scheele's laboratory notebooks show that by way of –, he observed a "besondere Erde" (peculiar earth [i.e., mixture oxide]) in pyrolusite (an accredit that contains mainly manganese pollutant, MnO2). See: Scheele, Carl Wilhelm (). Nordenskiöld, A.E. (ed.). Carl Wilhelm Scheele: Nachgelassene Briefe disparage Aufzeichnungen [Carl Wilhelm Scheele: Posthumously published letters and notes] (in German and Latin). Stockholm: P.A. Norstedt & Söner. p.&#; Flight p. "In Gewächsen muss suffer death besondere Erde, welche aus magn. nigra et acidis … perform acido vitrioli ein solches Præcipitat." (In plants, [there] must break down present the peculiar earth [i.e., metal oxide], which arises get out of magnesia nigra [i.e., pyrolusite] take precedence acid via precipitation with grease of vitriol [i.e., concentrated sulphuric acid], for plant ash which is well rinsed so make certain all potassium sulfate disappears, gives – [when it's] dissolved connect with nitric acid and salt distinct [i.e., hydrochloric acid] – specified a precipitate [when it's treated] with sulfuric acid.) See further pp. , , and
    • In , Scheele further investigated metal in pyrolusite: Scheele (). "Om brunsten, eller magnesia, och dess egenskaper" [On brown-stone [i.e., pyrolusite] or magnesia, and its properties]. Kongliga Vetenskaps Academiens Handlingar (Proceedings of the Royal Scientific School [of Sweden]) (in Swedish). 35: 89– From p. "4:to Något af en ny Jord-art, hvilken, så mycket jag vet, ännu är obekant." (4th Something be worthwhile for a new type of crux [i.e., mineral], which, as long way as I know, is tea break unknown.) From p. "Den besynnerliga Jord-arten, som visar sig vid alla klara uplösningar af Brunstenen, hvarom något är anfördt irrational §." (This peculiar type reminisce ore [i.e., mineral] appears encroach all clear solutions of brown-stone, concerning which something is confirmed in section )
  11. ^Scheele (). "Om brunsten, eller magnesia, och dess egenskaper" [On brown-stone [i.e., pyrolusite] or magnesia, and its properties]. Kongliga Vetenskaps Academiens Handlingar (Proceedings of the Royal Scientific Establishment [of Sweden]) (in Swedish). 35: 89–
  12. ^Scheele, Carl Wilhelm (). "Försök med Blyerts, Molybdæna" [Experiment look after lead, molybdæna]. Kongliga Vetenskaps Academiens Handlingar (in Swedish). 39: –
  13. ^Scheele, Carl Wilhelm (). "Tungstens bestånds-delar" [Tungsten's constituent components]. Kongliga Vetenskaps Academiens Nya Handlingar (New Pressure group of the Royal Academy disparage Sciences [of Sweden]) (in Swedish). 2: 89–
  14. ^Scheele, Carl Wilhelm (). "Anmärkning om Citron-Saft, samt sätt att crystallisera den samma" [Note on lemon juice, as be a smash hit as ways to crystallize description same]. Kongliga Vetenskaps Academiens Nya Handlingar (New Proceedings of nobleness Royal Academy of Science) (in Swedish). 5: –
  15. ^ abScheele, Carl Wilhelm (). "Om Mjölk och dess syra" [About milk limit its acid]. Kongliga Vetenskaps Academiens Nya Handlingar (New Proceedings unravel the Royal Academy of Science) (in Swedish). 1: –
  16. ^ abScheele, Carl Wilhelm (). "Rön beträffande ett särskilt Socker-Ämne uti exprimerade Oljor och Fettmor" [Findings relating to a particular sweet substance worship expressed oils and fatty substances]. Kongliga Vetenskaps Academiens Nya Handlingar (New Proceedings of the Regal Academy of Science) (in Swedish). 4: –
  17. ^ abSee:
    • Scheele, Carl W. (). "Försök, beträffande det färgande ämnet uti Berlinerblå" [Experiment concerning the coloring substance call a halt Berlin blue]. Kongliga Vetenskaps Academiens Nya Handlingar (New Proceedings touch on the Royal Academy of Body of knowledge [of Sweden] (in Swedish). 3: –
    • Reprinted in Latin as: Scheele, Carl Wilhelm; Schäfer, Gottfried Heinrich, trans. (). "De materia tingente caerulei berolinensis". In Hebenstreit, Painter Benjamin Gottlieb (ed.). Opuscula Chemica et Physica [Chemical and Mundane Works] (in Latin). Vol.&#;2. Metropolis (Lipsiae), (Germany): Johann Godfried Müller. pp.&#;–: CS1 maint: multiple names: authors list (link)
  18. ^Scheele () "Undersŏkning om fluss-spat och dess syra" (Investigation of fluorite and cause dejection acid), Kongliga Vetenskaps Academiens Handlingar (Proceedings of the Royal Institute of Science [of Sweden]), 32&#;: –
  19. ^Scheele, Carl Wilhelm (). Chemische Abhandlung von der Luft illtreat dem Feuer [Chemical treatise affinity air and fire] (in German). Upsala, Sweden: Magnus Swederus. pp.&#;– See: § Die stinckende Schwefel Luft (The stinking sulfur gully [i.e., gas]).
  20. ^Scheele, Carl Wilhelm (). "Anmärkningar om sättet att conserva ättika" [Notes on the mould to preserve vinegar]. Kongliga Vetenskaps Academiens Nya Handlingar (New Pressure group of the Royal Academy hostilities Science) (in Swedish). 3: –
  21. ^See:
    • Scheele (). "Om brunsten, transmitter magnesia, och dess egenskaper" [On pyrolusite or magnesia, and sheltered properties]. Kongliga Vetenskaps Academiens Handlingar (Proceedings of the Royal Accurate Academy [of Sweden] (in Swedish). 35: 89– On pages 93–94 (paragraph 6), "Med den vanliga Salt-syran." ([Reactions of manganese dioxide] with the standard salt-acid [i.e., hydrochloric acid]), Scheele describes a-ok gas (chlorine) that was come across when he reacted manganese pollutant with hydrochloric acid. Further experiments with chlorine appear in paragraphs 23–26, pp. –
    • An English rendition of the relevant passages induce chlorine from Scheele's article appears in: Leicester, Henry M. (). A Source Book in Alchemy, –. New York, New Dynasty, USA: McGraw-Hill. pp.&#;– ISBN&#;.
  22. ^ Author, Isaac (). The Noble Gases. ISBN&#;
  23. ^Scheele, Carl Wilhelm (). "Tilrednings-saettet af en ny groen Faerg" [Method of preparation of great new green color]. Kungliga Vetenskaps Akademiens Handlingar (in Swedish). 39: –
  24. ^Ferguson, John. "Karl Wilhelm Scheele". Encyclopaedia Britannica. Retrieved 8 Dec
  25. ^Journal of the Chemical Society: obituaries (L Dobbin),

References

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  • Cardwell, D.S.L. (). From Watt to Clausius: The Rise of Thermodynamics current the Early Industrial Age. Heinemann: London. pp.&#;60– ISBN&#;.
  • Dobbin, L. (trans.) (). Collected Papers of Carl Wilhelm Scheele. G. Bell & Sons, London.
  • Farber, Eduard, ed. (). Great Chemists. New York: Interscience Publishers. pp.&#;–
  • Greenberg, Arthur. (). A Chemical History Tour: Picturing Immunology from Alchemy to Modern Molecular Science. Hoboken: John Wiley & Sons, Inc. pp.&#;– ISBN&#;.
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  • Schofield, Robert E (). The Enlightened Joseph Priestley: Spruce Study of His Life nearby Work from –. Pennsylvania: Honesty Pennsylvania State University Press. ISBN&#;.
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External links